Correction for ''Modulation of the mechanical energy storage performance of the MIL-47(VIV) metal organic framework by ligand functionalization'' by Pascal G. Yot et al., Dalton Trans., 2019, DOI: 10.1039/c8dt04214d.
Metal- salen polymers are electrochemically active metallopolymers functionalized with multiple redox centers, with a potential for high performance in various fields such as heterogeneous catalysis, chemical sensors, energy conversion, saving, and storage. In light of the growing world demand for the development of superior energy storage …
Energy Storage Science and Technology ›› 2022, Vol. 11 ›› Issue (2): 409-433. doi: 10.19799/j.cnki.2095-4239.2021.0652 • Invited paper • Previous Articles Next Articles Understanding and performance prediction of ions-intercalation electrochemistry: From
1 DOI: 10.1002/((please add manuscript number)) Article type: Communication Nanostructured Metal-Organic Conjugated Coordination Polymers with Ligand Tailoring for Superior Rechargeable Energy Storage Jian Xie, …
Iron (III)-Iron (II) complexes with o-phenanthroline and related ligands have been examined by electrochemical techniques in aqueous H2SO4 media with respect to their suitability as redox couples for electrochemical energy storage. The iron (II) complexes undergo a ...
Nanostructured metal‐organic conjugated coordination polymers with ligand tailoring for superior rechargeable energy storage. Small, 15(49), 1903188‐. …
A strategy of building compact 2D/2D superlattice films based on molecular ligand-mediated assembly of colloidal nanosheets is presented. Thanks to their densely packed nature and high stacking ordering, co-assembled MXene-rGO laminate films exhibit arguably the highest volumetric energy density ever reported for MXene-based …
Salphen-type nickel Schiff bases Ni(salphen), Ni(CH3-salphen), and Ni(CH3O-salphen) are synthesized and electropolymerized on stable ITO electrode, respectively. The morphologies of the three polymer electrodes were evaluated by field emission scanning electron microscopy (FESEM). X-ray photoelectron spectroscopy …
For society to embrace the notions of clean energy production and consumption, feasible systems for energy conversion and energy storage need to be developed. Electric double-layer capacitors (EDLC) are an effective means of energy storage, as they are able to stockpile and rapidly release large amounts of energy in …
The ligand extended MIL-53 (Al) MOFs provide higher water transfer between humid (relative humidity RH of 80% to 90%) and regenerated (RH of 30%) conditions with promising thermal energy storage density (TESD, up to 1.54 MJ/L).
Moreover, the as-fabricated binder-free symmetric supercapacitors show a high volumetric energy density of 42.1 Wh L −1, which is among the best reported for MXene-based materials in aqueous electrolytes. This work paves the way toward rational design of 2D
We herein demonstrate the fabrication of Mn- and Ni-based ultrathin metal–organic framework nanosheets with the same coordination mode (termed "Mn-UMOFNs" and "Ni-UMOFNs", respectively) through an expedient and versatile ultrasonic approach and scrutinize their electrochemical properties as anode materials for …
A strategy of building compact 2D/2D superlattice films based on molecular ligand-mediated assembly of colloidal nanosheets is presented. Thanks to their densely …
Charge-Transfer Effects of Organic Ligands on Energy Storage Performance of Oxide Nanoparticle-Based Advanced Functional Materials ( IF 19.0) Pub Date : 2021-09-09, DOI: 10.1002/adfm
Charge transfer kinetics within nanoparticle‐based energy electrodes play a decisive role in achieving higher output performance. In article number 2002969, Seung Woo Lee, Jinhan Cho and co ...
Lithium‑sulfur batteries (LSBs) are a developing energy storage system due to their low synthesis cost, high theoretical capacity and energy density, high storage ability, and safety [131, 132]. The sulfur to Li 2 S conversion reaction in LSBs is where the enormous capacity originates.
Poly (ethylene glycol) (PEG), as one of the most attractive organic PCMs, has been intensively studied due to its remarkable merits of high energy storage capacity, appropriate phase change ...
This study demonstrates the synergistic effect of a number of factors that increase the energy storage property, such as high porosity brought on by the proper …
Energy conversion is a prime concern of the scientific community and industrial sectors around the world 1,2,3.Among the various stimuli, light is a clean energy source which is both safe and ...
A strategy of building compact 2D/2D superlattice films based on molecular ligand‐mediated assembly of colloidal nanosheets is presented. Thanks to their densely packed nature and high stacking order...
,(NSs),。 …
The irradiated sample with 1 × 10 14 ions/cm 2, 1 × 10 15 ions/cm 2 and 5 × 10 14 ions/cm 2 revealed bandgap energy of 2.52 to 2.87 eV which is suitable energy storage application. Zeolitic imidazolate frameworks (ZIFs): Advanced nanostructured materials to enhance the functional performance of food packaging materials
Metal–organic frameworks are linked by different central organic ligands and metal-ion coordination bonds to form periodic pore structures and rich pore volumes. Because of their structural advantages, metal–organic frameworks are considered to be one of the most promising candidates for new energy storage materials. To better utilize their …
A general methodology that exploits long-chain molecular ligands to induce ordered assembly of colloidal nanosheets (NSs), resulting in 2D laminate superlattices with high packing density and paves the way toward rational design of 2D material-based superstructures for energy applications. Inspired by the self-assembly of nanoparticle …
V vs. Li + /Li, it was supposed that two-electron reduction of the ligands was followed by reduction of Ni 2+ to Ni 0, and no NH-proton substitution occurred. 14 However, the experimental ...
An electrolyte design using small-sized fluoroacetonitrile solvents to form a ligand channel produces lithium-ion batteries simultaneously achieving high energy …
A strategy of building compact 2D/2D superlattice films based on molecular ligand‐mediated assembly of colloidal nanosheets is presented. Thanks to their densely packed nature and high stacking ordering, co‐assembled MXene‐rGO laminate films exhibit arguably the highest volumetric energy density ever reported for MXene‐based …
Design and synthesis of mixed-ligand architectured Zn-based coordination polymers for energy storage T. K. Ghosh and G. Ranga Rao, Dalton Trans., 2023, 52, 5943 DOI: 10.1039/D3DT00518F
Herein, we introduce a redox-active ligand-mediated layer-by-layer (LbL) assembly as a novel approach for significantly enhancing the energy storage performance of TMO NP-based pseudocapacitor ...
In particular, hydrazine ligands, which have extremely small molecular size and strong chemical reducing properties, can effectively remove bulky organic …
Ligands induced NiS 2 quantum dots for synchronous high specific capacity and robust stability of advanced electrochemical energy storage Author links open overlay panel Wenyong Chen a b, Xuemei Zhang b c, Li-E Mo a, Zhenzhen Feng b c, Shuanghong Chen a, Xianxi Zhang d, Yongsheng Zhang c, Linhua Hu a
An innovative tailoring strategy is presented toward the enhancement of the capacity storage and the stability of metal–organic conjugated coordination polymers. Two …
Many materials Commonly used materials for energy storage, such as transition metal oxides (TMOs), metal sulfides ... nitrate (49.91 mg, 0.25 mmol) were dissolved in 3 mL of the above mixture. The Ligand and metal salt solutions were mixed with a …
One of the most difficult challenges related to pseudocapacitive nanoparticle (PC NP)‐based energy storage electrodes with theoretically high capacity is to overcome the sluggish charge‐transfer kinetics that result from the poorly conductive PC NPs and bulky/insulating organics (i.e., organic ligands and/or polymeric binders) within the …
In addition to their many well-known advantages (e.g., ultra-high porosity, good pore size distribution, easy functionalization, and structural tolerability), metal-organic frameworks (MOFs) are a new class of advanced functional materials. However, their backbones are highly susceptible to deformation after exposure to acidic or alkaline …
MIL-47(VIV)-BDC-CF3 was demonstrated to be one of the most promising porous materials for mechanical energy-related applications with performance in terms of work energy which surpasses that of any porous solids reported so far. The functionalization of the metal-organic framework MIL-47(VIV) with ligands bearing bulky functional groups …
Coordination polymers represent a suitable model to study redox mechanisms in materials where both metal cation and ligand undergo electrochemical reactions and are capable to proceed through reversible multielectron-transfer processes with insertion of cation and anion into their open structures. Designing new coordination …
An innovative tailoring strategy toward the enhancement of the capacity storage and stability of d‐π metal‐organic conjugated coordination polymers is proposed. The tailored compound Ni‐S shows a hig...